(Methanolato)(pyridine)[N 2,N 2′-(pyridine-2,6-diyldicarbonyl)diacetohydrazide(2–)]iron(III) methanol solvate
نویسندگان
چکیده
In the title complex, [Fe(C(11)H(10)N(5)O(4))(CH(3)O)(C(5)H(5)N)]·CH(4)O, the Fe(III) ion has a distorted penta-gonal-bipyramidal geometry. In the crystal structure, mol-ecules are linked into one-dimensional chains along [1] via inter-molecular O-H⋯O and N-H⋯O hydrogen bonds.
منابع مشابه
Bis[N-(2-pyridylcarbonyl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl-carbon-yl)pyridine-2-carboximidate (bpca) ligands and exhib-its a distorted octa-hedral coordination by six bpca N atoms. A classical O-H⋯O hydrogen bond exists between the methanol solvent mol-ecule and the perchlorate anion. Magnetic susceptibility measurements indica...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007